Categories: S-S Bond Formation > Synthesis of Trisulfides

Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S ...AU - Coucouvanis,D.AU - Kanatzidis,M.AU - Simhon,E.AU - Baenziger,N.

Its reactions with dibenzyl trisulfide and the synthesis of the [Fe4S4Cl4]2- and [Fe4S ...

In reactions where the dibenzyl trisulfide to I ratio exceeds 4, the [Fe4S4Cl4]2- (III) "cubane"-type cluster forms and can be isolated in excellent yields when the reagent ratio is 8:1.AB - Full title: Synthesis, molecular structure, and reactions of bis(tetraphenylphosphonium) hexakis(μ-thiophenolato)-tetrachlorotetraferrate(II), (Ph4P)2[Fe4(SPh)6Cl4].


trisulfide synthesis essay - BioAlabama